Influence of 0.25% Indium Addition to Ni/CeO₂ Catalysts for Dry Reforming of Methane

Abstract

In this study, the surface and textural properties as well as the catalytic performance of Ni/CeO2 and NiIn/CeO2 catalysts prepared by wet impregnation (WI) and deposition–precipitation (DP) are investigated. The addition of Ni (3.0 wt.%) resulted in a decrease in the specific surface area and pore volume in the case of the WI method, possibly due to a blockage of mesopores. A minimal addition of In (0.25 wt.%) caused a further decrease in the surface area in both cases. XRD analysis showed that Ni deposited on CeO2 by DP resulted in some lattice incorporation, affecting the crystallinity of the support. The H2-TPR profiles altered depending on the different ways of Ni and In introduction. STEM-EDS-derived elemental maps indicated that the Ni and NiIn particles deposited on CeO2 using the DP method were somewhat smaller than in the WI synthesis. A comprehensive CO-DRIFTS analysis proved a direct Ni-In interaction in bimetallic samples, leading to the formation of a surface NiIn alloy. Ni/CeO2 catalysts showed a higher activity in the process of dry reforming of methane (DRM) than the bimetallic counterparts at 650 °C, with the Ni_DP sample performing slightly better. However, the Ni_DP catalyst showed significant coking, which was drastically reduced by the addition of In. The agglomeration of Ni and/or NiIn particles during the 6 h DRM reaction somewhat impaired the catalyst performance. Overall, this study highlights the intricate relationship between the catalyst preparation, surface properties and catalytic performance in the DRM reaction and emphasizes the beneficial role of In addition in reducing the coking of the monometallic catalyst and the critical location and surface morphology of nickel nanoparticles decorated with indium and in contact with ceria.

Keywords

• dry reforming of methane
• bimetallic catalysts
• In-Ni/CeO₂
• heterogeneous catalysis
• CO₂ utilization