The Role of TiO₂ during the Accelerated Aging of Recycled Rubber Tiles

Abstract

Titanium dioxide (TiO2) was added in different proportions as a filler to the mixture for the production of recycled rubber tiles in order to improve their existing properties. The mechanical properties of novel rubber tiles were analyzed in the context of abrasion resistance, maximum stress (TS), stress at break (TSb), deformation at break (Eb), and hardness. An optimal mixture composition was found comparing the obtained results of mechanical tests; successful improvement of abrasion by 22.1%, Eb by 10.46% and hardness by 17.65% was achieved. Finally, the characterization of the new rubber tile by SEM/EDS and FTIR analysis was carried out, along with the stability and environmental impact assessment based on the leaching test. The accelerated aging test was conducted using a solar simulator, after which the mechanical properties, SEM/EDS, FTIR, and leaching test were re-examined. The results after the accelerated aging test showed that tiles with the addition of TiO2 have better mechanical properties compared to the reference ones; TS improved by 85.71%, Eb by 75.53%, and hardness by 9.43%. Therefore, we concluded that TiO2 as a filler in interaction with rubber and polyurethane composites significantly contributed to the improvement of the existing rubber tile, and the achieved improvements are useful for the original application of these tiles, which is the protection from injuries on playgrounds and sports fields. Also, the improvement achieved extends the service life of this type of tile, which contributes to the quality of this type of material.

Keywords

• recycled rubber
• titanium dioxide
• polymer
• accelerated aging