Lithium and brine geochemistry in the Qianjiang Formation of the Jianghan Basin, central China

Abstract

Abstract The Li-enriched oilfield brine is a very important lithium resource. It has gained much attention and become the target of active Li surveys with the growing global demand for Li. However, only little is known about their feature and nature. In the study, hydrochemical data from 155 oil wells tapping the Eocene to Lower Oligocene Qianjiang Formation of the Jianghan Basin, central China indicate that the brines are of the Na–Cl or Na–Ca–Cl type and are characterized by highly variable Li contents of 7.56 to 150 mg/L, with Mg/Li ratios less than 11.65. High Na/Cl and Cl/Br molar ratios indicate distinct contributions from halite dissolution. The Ca excess, Na deficit and Ca/Mg and Ca/Sr molar ratios in the brines imply multiple diagenetic processes, including halite dissolution, dolomitization, albitization and calcite or anhydrite cementation. The lithium contents of these brines have a weak relationship with the salinity and a negative correlation with Cl/Br ratios, possibly indicating that these Qianjiang oilfield brines have been diluted by secondary brines derived from halite dissolution. The spatial distribution patterns for Li and B concentrations of the brines are different from those for salinity and Br contents and show a geographic pattern, indicating that Li enrichment in the Qianjiang brines is likely connected with geothermal sources associated with volcanic activity.