A connected graph Γ is k-extendable for a positive integer k if every matching M of size k can be extended to a perfect matching. The extendability number of Γ is the maximum k such that Γ is k-extendable. In this paper, we prove that Cayley graphs generated by transposition trees on {1,2,…,n} are (n−2)-extendable and determine that the extendability number is n−2 for an integer n≥3.