SnOx@β–SnO heterostructures and their enhanced photocurrent in photoelectrochemical cell

Abstract

To improve the effective separation of the photogenerated electrons and holes, SnO _x @ β –SnO composites on titanium meshes were prepared by using a standard one-step hydrothermal procedure. As photoanodes in photoelectrochemical cell, the SnO _x @ β –SnO composites exhibited a photocurrent density of 150 μ A cm ^−2 at 0.0 V versus Ag/AgCl under visible light illumination. The improved photocurrent can be explained as, the Sn ^2+ 5s impurity states in SnO _2 have a band gap energy of 2.24 eV, SnO _x @ β –SnO composites construct a type-II heterojunction. And titanium meshes have a good conductivity, which is beneficial to transferring electron from the conduction band of SnO _2 to external circuit. Furthermore, the SnO _x @ β –SnO heterostructures have a larger electrochemical specific surface area, and stronger light absorption from 350–800 nm.

Keywords

• SnOx@β–SnO
• Sn2+ doped
• photoelectrochemical cell
• photocurrent
• heterostructure