Crystal structure, Hirshfeld and electronic transition analysis of 2-[(1H-benzimidazol-1-yl)methyl]benzoic acid

Arif Ali; Mohd Muslim; Saima Kamaal; Adeeba Ahmed; Musheer Ahmad; M. Shahid; Jamal A. Khan; Necmi Dege; Saleem Javed; Ashraf Mashrai

doi:10.1107/S2056989021006435

Acta Crystallographica Section E: Crystallographic Communications (Jul 2021)

Crystal structure, Hirshfeld and electronic transition analysis of 2-[(1H-benzimidazol-1-yl)methyl]benzoic acid

Arif Ali,
Mohd Muslim,
Saima Kamaal,
Adeeba Ahmed,
Musheer Ahmad,
M. Shahid,
Jamal A. Khan,
Necmi Dege,
Saleem Javed,
Ashraf Mashrai

Affiliations

Arif Ali: Department of Applied Chemistry, Faculty of Engineering and Technology, ZHCET, Aligarh Muslim University, Aligarh 202002 (UP), India
Mohd Muslim: Department of Applied Chemistry, Faculty of Engineering and Technology, ZHCET, Aligarh Muslim University, Aligarh 202002 (UP), India
Saima Kamaal: Department of Applied Chemistry, Faculty of Engineering and Technology, ZHCET, Aligarh Muslim University, Aligarh 202002 (UP), India
Adeeba Ahmed: Department of Applied Chemistry, Faculty of Engineering and Technology, ZHCET, Aligarh Muslim University, Aligarh 202002 (UP), India
Musheer Ahmad: Department of Applied Chemistry, Faculty of Engineering and Technology, ZHCET, Aligarh Muslim University, Aligarh 202002 (UP), India
M. Shahid: Functional Inorganic Materials Lab (FIML), Department of Chemistry, Aligarh, Muslim University, Aligarh 202002, India
Jamal A. Khan: Department of Applied Chemistry, Faculty of Engineering and Technology, ZHCET, Aligarh Muslim University, Aligarh 202002 (UP), India
Necmi Dege: Ondokuz Mayis University, Faculty of Arts and Sciences, Department of, Physics,55139 Samsun, Turkey
Saleem Javed: Department of Chemistry, Institute of H. Science, Dr. Bhimrao Ambedkar, University, Agra 282002, U. P., India
Ashraf Mashrai: Department of Pharmacy, University of Science and Technology, Ibb branch, Yemen

DOI: https://doi.org/10.1107/S2056989021006435
Journal volume & issue: Vol. 77, no. 7
pp. 755 – 758

Abstract

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In the title compound, C15H12N2O2, the benzimidazole ring system is inclined to the benzene ring by 78.04 (10)°. The crystal structure features O—H...N and C—H...O hydrogen bonding and C—H...π and π–π interactions, which were investigated using Hirshfeld surface analysis.

Published in Acta Crystallographica Section E: Crystallographic Communications

ISSN: 2056-9890 (Online)
Publisher: International Union of Crystallography
Country of publisher: United Kingdom
LCC subjects: Science: Chemistry: Crystallography
Website: https://journals.iucr.org/e/

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