Selective photocatalytic CO2 reduction in aerobic environment by microporous Pd-porphyrin-based polymers coated hollow TiO2

Yajuan Ma; Xiaoxuan Yi; Shaolei Wang; Tao Li; Bien Tan; Chuncheng Chen; Tetsuro Majima; Eric R. Waclawik; Huaiyong Zhu; Jingyu Wang

doi:10.1038/s41467-022-29102-0

Nature Communications (Mar 2022)

Selective photocatalytic CO2 reduction in aerobic environment by microporous Pd-porphyrin-based polymers coated hollow TiO2

Yajuan Ma,
Xiaoxuan Yi,
Shaolei Wang,
Tao Li,
Bien Tan,
Chuncheng Chen,
Tetsuro Majima,
Eric R. Waclawik,
Huaiyong Zhu,
Jingyu Wang

Affiliations

Yajuan Ma: Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology
Xiaoxuan Yi: Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology
Shaolei Wang: Key Laboratory of Polyoxometalate Science of Education Institution, Faculty of Chemistry, Northeast Normal University
Tao Li: Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology
Bien Tan: Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology
Chuncheng Chen: Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences
Tetsuro Majima: Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology
Eric R. Waclawik: School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology
Huaiyong Zhu: School of Chemistry, Physics and Mechanical Engineering, Queensland University of Technology
Jingyu Wang: Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education), School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology

DOI: https://doi.org/10.1038/s41467-022-29102-0
Journal volume & issue: Vol. 13, no. 1
pp. 1 – 10

Abstract

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While selective CO2 reduction is crucial for its removal from the environment, the presence of O2 hinders this process. Here authors show CO2 photoreduction in the presence of O2 by incorporating Pd(II) sites into a coordination polymer on TiO2 to selectively adsorb CO2.

Published in Nature Communications

ISSN: 2041-1723 (Online)
Publisher: Nature Portfolio
Country of publisher: United Kingdom
LCC subjects: Science
Website: https://www.nature.com/ncomms/

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