Laboratory of Organic Synthesis and Physico-Molecular Chemistry, Department of Chemistry, Faculty, Sciences Semlalia, BP 2390, Marrakech 40001, Morocco
Aziz Auhmani
Laboratory of Organic Synthesis and Physico-Molecular Chemistry, Department of Chemistry, Faculty, Sciences Semlalia, BP 2390, Marrakech 40001, Morocco
Moulay Youssef Ait Itto
Laboratory of Organic Synthesis and Physico-Molecular Chemistry, Department of Chemistry, Faculty, Sciences Semlalia, BP 2390, Marrakech 40001, Morocco
Abdelkhalek Riahi
Institute of Molecular Chemistry of Reims, CNRS UMR 7312 Bat. Europol'Agro, Moulin of the Housse UFR Sciences, BP 1039-51687 Reims Cedex 2, France
Sylviane Chevreux
Institute of Molecular Chemistry of Reims, CNRS UMR 7312 Bat. Europol'Agro, Moulin of the Housse UFR Sciences, BP 1039-51687 Reims Cedex 2, France
El Mostafa Ketatni
Laboratory of Applied Spectro-Chemistry and Environment, University Sultan Moulay Slimane, Faculty of Science and Technology, PO Box 523, Beni-Mellal, Morocco
There are two independent molecules (A and B) in the asymmetric unit of the title compound, C11H19N3S. In molecule B, two C atoms and the associated H atoms of the cyclohexene ring are disordered over two sets of sites with a site occupancy ratio of 0.649 (7):0.351 (7). The N—N—C—N fragments of the hydrazinecarbothioamide segments of both molecules are not planar, with a torsion angle of −5.8 (3)° for A and 11.6 (3)° for B. The stability of the conformations of both molecules is aided by the formation of intramolecular N—H...N hydrogen bonds. In the crystal, N—H...S hydrogen bonds link like molecules into R22(8) A + B dimers. These dimers are interconnected by additional N—H...S contacts, forming chains along the c-axis direction. The structure was refined as a two-component inversion twin.
