Flotation Separation of Chalcopyrite and Talc Using Calcium Ions and Calcium Lignosulfonate as a Combined Depressant

Abstract

As a major gangue mineral in sulfide ores, talc is difficult to separate from chalcopyrite in the flotation process due to its natural floatability, which affects the subsequent smelting process. In this study, the effects of calcium ions and calcium lignosulfonate (CLS) as a combination depressant for talc were systematically investigated along with the fundamental mechanisms. The results of our flotation tests showed the talc floating can be effectively depressed via the combination depressant effect of calcium ions and CLS over the pH range of 6–12. Measurements of the adsorption capacity, zeta potential, and Fourier transform infrared (FTIR) showed an enhancement of the adsorption capacity and adsorption strength of CLS on the talc surface after calcium ions were added. This result indicates that calcium ions adsorbed onto the talc, neutralized the negative charge on the surface of talc, generated the binding site with CLS, and formed the [talc-Ca2+/Ca(OH)+-CLS] system by strong adsorption. Further, the coverage rate of CLS on talc was significantly improved after the addition of calcium ions, as shown in the AFM imaging.

Keywords

• chalcopyrite
• talc
• calcium lignosulfonate
• calcium ion
• adsorption