Design and Fabrication of High Activity Retention Al-Based Composite Powders for Mild Hydrogen Generation

Abstract

Al−Bi−Sn−Cu composite powders for hydrogen generation were designed from the calculated phase diagram and prepared by the gas atomization process. The morphologies and structures of the composite powders were investigated using X-ray diffraction (XRD) and a scanning electron microscope (SEM) equipped with energy-dispersive X-ray (EDX) spectroscopy, and the results indicate that the Cu additive enhanced the phase separation between the Al-rich phase and the (Bi, Sn)-rich phase. The hydrogen generation performances were investigated by reacting the materials with distilled water. The Al−Bi−Sn−Cu powders reveal a stable hydrogen generation rate, and the Al−10Bi−7Sn−3Cu (wt%) powder exhibits the best hydrogen generation performance in 50 °C distilled water which reaches 856 mL/g in 800 min. In addition, the antioxidation properties of the powders were also studied. The Al−10Bi−7Sn−3Cu (wt%) powder has a good resistance to oxidation and moisture, which shows great potential for being the hydrogen source for fuel cell applications.

Keywords

• hydrogen generation
• aluminum
• hydrolysis reaction
• gas atomization