Phase engineering of transition metal compounds for boosting lithium/sodium storage
Xiaofeng Li,
Jinzhen Huang,
Ran Wang,
Li Zhao,
Yumin Zhang,
Tangling Gao,
Tai Yao,
Bo Song
Affiliations
Xiaofeng Li
School of Physics, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
Jinzhen Huang
National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
Ran Wang
National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
Li Zhao
China Aerospace Academy of Architectural Design & Research Co., Ltd., Beijing, People’s Republic of China
Yumin Zhang
National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
Tangling Gao
Institute of Petrochemistry, Heilongjiang Academy of Sciences, Harbin 150040, People’s Republic of China
Tai Yao
National Key Laboratory of Science and Technology on Advanced Composites in Special Environments, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
Bo Song
School of Physics, Harbin Institute of Technology, Harbin 150001, People’s Republic of China
The rapid development of lithium ion batteries (LIBs) and sodium ion batteries (SIBs) requires novel anode materials with high performance. Phase engineering has been regarded as a promising strategy used for enhancing the electrochemical performance of LIBs and SIBs due to its superiority of selectively synthesizing the phases with favorable electrochemical performance and reasonably designing the electrode materials with multiphase regulation. Recently, much progress has been made in phase engineering, including the strategies of phase transition and applications of phase engineering in lithium/sodium storage. This Research Update summarizes the structure and electrical characteristics of transition metal compounds with multiple phases, various strategies for their phase transition engineering, and advanced applications in lithium/sodium storage. Moreover, we also offer general perspectives on current obstacles and future chances in this emerging field, including exploration on the sodium/lithium storage mechanism toward different phases, understanding on structure–mechanism–performance relationships in conjunction with theoretical and experimental research, development of new materials with phase transition and new phase transition strategies, and design of a phase interface (phase junction) with novel phase engineering.
