Acta Crystallographica Section E (Jan 2013)

3-Hydroxy-1-(4-methoxybenzyl)piperidin-2-one

  • Joseph P. Michael,
  • Charles B. de Koning,
  • Sanaz Khorasani,
  • Daniel P. Pienaar

DOI
https://doi.org/10.1107/S1600536812049501
Journal volume & issue
Vol. 69, no. 1
pp. o51 – o51

Abstract

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The title compound, C13H17NO3, adopts a conformation in which the aromatic ring and the mean plane of the piperidine ring are almost perpendicular to each other [dihedral angle = 79.25 (6)°]. The presence of the carbonyl group alters the conformation of the piperidine ring from a chair to a twisted half-chair conformation. In the crystal, pairs of strong O—H...O hydrogen bonds link the molecules into inversion dimers. Weak C—H...O interactions extend the hydrogen-bonding network into three dimensions.