Materials Research ()

Application of Zinc Oxide in Hybrid Solar Cells Using a P3HT and P3OT Polymer Junction as Charge Carrier

  • Letícia Fernanda Gonçalves Larsson,
  • Guilherme Arielo Rodrigues Maia,
  • Gideã Taques Tractz,
  • Tatiana Lima Valério,
  • Danielle Cristina Silva Oliszeski,
  • Rodrigo Helleis,
  • Maico Taras da Cunha,
  • Paulo Rogério Pinto Rodrigues,
  • Everson do Prado Banczek

DOI
https://doi.org/10.1590/1980-5373-mr-2018-0820

Abstract

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Hybrid solar cells show an increasing number in researches due to its low cost and easy of production. They are composed by and organic material and a semiconductor oxide. The aim of this paper was to synthesis and characterize zinc oxide by coprecipitation and apply it in a hybrid solar cell that uses a P3HT/P3OT copolymer as charge carrier. The cell was assembled in "sandwich" form using FTO/ZnO/P3HT-P3OT as work electrode, (Pt/FTO) as conter electrode and I/I-3 redox couple as electrolyte. Through the X-ray diffractogram the formation of a single ZnO wutzite hexagonal phase was observed. The morphology obtained for the oxide was spherical. The results of photochronoamperometry showed current density values of jP3HT/P3OT =0.55 mA.cm-2 for the cell in the presence of the copolymer and the curve jxV showed an efficiency of 0.16% for the studied cell, demonstrating that the polymer was a satisfactory sensitizer.

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