A Study on Gel/Space Ratio Development in Binary Mixture Containing Portland Cement and Meta-Illite Calcined Clay/Rice Husk Ash

Abstract

Supplementary cementitious materials (SCMs) have been widely used to enhance both the microscopic and macroscopic properties of the Portland cement (PC)–SCM composite matrix. Few studies have been undertaken to establish the gel/space ratio of meta-illite calcined clay (MCC) and rice husk ash (RHA)-based high-performance concrete (HPC) mortar. This experimental paper describes a conventional degree of hydration (non-evaporable water) and porosity routes of establishing a link amid the gel/space ratio and compressive strength of a sieved mortar from Class 1 (50–75 MPa) HPC at an early age. Using the non-evaporable water method, this paper predicted the gel/space ratio of the hardened MCC/RHA-based HPC mortars and curved fitted into Powers’ exponent equation. The results from this study revealed that MCC or RHA additions (5–30% by weight of PC) to the PC-SCM matrix led to a moderate decline in the compressive strength of the low water-binder ratio (W/B) HPC mortar. The modification aimed at void volume (superabsorbent polymers, SAP, and air) applying Bolomey’s formula and Powers’ gel/space ratio developed a suitable fitting into the Powers’ model. This experimental procedure shows feasibility to predict the MCC and RHA outcome on the compressive strength of HPC.

Keywords

• gel/space ratio
• meta-illite calcined clay
• rice husk ash
• Powers’ model
• high-performance concrete
• superabsorbent polymers