Materials (Dec 2022)

Effect of Hydrogen Exposure Temperature on Hydrogen Embrittlement in the Palladium–Copper Alloy System (Copper Content 5–25 wt.%)

  • Brandon Roy,
  • Erin LaPointe,
  • Andrew Holmes,
  • Dillon Camarillo,
  • Bonolo Jackson,
  • Daniel Mathew,
  • Andrew Craft

DOI
https://doi.org/10.3390/ma16010291
Journal volume & issue
Vol. 16, no. 1
p. 291

Abstract

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The yield strength, ultimate strength, and elongation/ductility properties of a series of palladium–copper alloys were characterized as a function of the temperature at which each alloy underwent absorption and desorption of hydrogen. The alloys studied ranged in copper content from 5 weight percent copper to 25 wt.% copper. Compared to alloy specimens that had been well-annealed in a vacuum and never exposed to hydrogen, alloys with copper content up to 15 wt.% showed strengthening and loss of ductility due to hydrogen exposure. In these alloys, it was found that the degree of strengthening and loss of ductility was dependent on the hydrogen exposure temperature, though this dependence decreased as the copper content of the alloy increased. For alloys with copper contents greater than 15 wt.%, hydrogen exposure had no discernible effect on the strength and ductility properties compared to the vacuum-annealed alloys, over the entire temperature range studied.

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