Glycols in the Synthesis of Zinc-Anilato Coordination Polymers
Olesya Y. Trofimova,
Arina V. Maleeva,
Kseniya V. Arsenyeva,
Anastasiya V. Klimashevskaya,
Il’ya A. Yakushev,
Alexandr V. Piskunov
Affiliations
Olesya Y. Trofimova
Laboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, Russia
Arina V. Maleeva
Laboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, Russia
Kseniya V. Arsenyeva
Laboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, Russia
Anastasiya V. Klimashevskaya
Laboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, Russia
Il’ya A. Yakushev
N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia
Alexandr V. Piskunov
Laboratory of Metal Complexes with Redox-Active Ligands, G.A. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, 603137 Nizhny Novgorod, Russia
We report the synthesis, structural investigation, and thermal behavior for three zinc-based 1D-coordination polymers with 3,6-di-tert-butyl-2,5-dihydroxy-p-benzoquinone, which were synthesized in the presence of different glycols. The interaction of zinc nitrate with glycols, followed by using the resulting solution in solvothermal synthesis with the anilate ligand in DMF, makes it possible to obtain linear polymer structures with 1,2-ethylene or 1,2-propylene glycols coordinated to the metal. The reaction involving 1,3-propylene glycol under similar conditions gives a crystal structure that does not contain a diol. The crystal and molecular structures of the synthesized compounds were determined using single crystal by X-ray structural analysis. The influence of glycol molecules coordinated to the metal on the thermal destruction of synthesized compounds is shown.
