Two-dimensional materials as sodium-ion battery anodes: The mass transfer and storage mechanisms of “fat” Na+
Yuan Shao,
Yong Zhang,
Na Jiang,
Yuhan Hao,
Keqi Qu,
You Zeng,
Ziqiang Liu,
Xuejun Lu,
Ying Li,
Qi Yang,
Jieshan Qiu
Affiliations
Yuan Shao
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China; New Energy Battery Division, Hengdian Group DMEGC Magnetics Co., Ltd., Dongyang, Zhejiang 322117, China
Yong Zhang
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Na Jiang
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Yuhan Hao
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Keqi Qu
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
You Zeng
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Ziqiang Liu
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Xuejun Lu
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China; Corresponding author
Ying Li
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
Qi Yang
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China; Corresponding author
Jieshan Qiu
State Key Laboratory of Chemical Resource Engineering, College of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China; Corresponding author
Summary: Sodium-ion batteries (SIBs) with abundant resource and high safety are attracting intensive interest from both research and industry communities in meeting the ever-increasing energy demands. Despite the rapid advance of SIBs, it is difficult yet necessary to enhance the cycling and rate performance at anode due to the sluggish kinetics of “fat” Na+. This review provides an overview of two-dimensional (2D) nanomaterials with a short ion diffusion pathway and a superior active sites exposure from the perspectives of synthesis, material chemistry, and structure engineering. We present the design principle of ideal carbon materials in SIBs. Moreover, we discuss the structure and chemistry regulations of different 2D materials to promote the efficient ion mass transfer and storage according to the different mechanisms of alloying, conversion, and insertion. Finally, we propose the remaining challenges and the possible solutions, in hope of guiding the future development of this booming field.
