Enhancing the electrochemical performance of semicoke‐based hard carbon anode through oxidation‐crosslinking strategy for low‐cost sodium‐ion batteries
Huizhen Ma,
Yakun Tang,
Bin Tang,
Yue Zhang,
Limin Deng,
Lang Liu,
Sen Dong,
Yuliang Cao
Affiliations
Huizhen Ma
State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources; College of Chemistry Xinjiang University Urumqi Xinjiang China
Yakun Tang
State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources; College of Chemistry Xinjiang University Urumqi Xinjiang China
Bin Tang
School of Chemical Engineering, Interdisciplinary Research Center for Sustainable Energy Science and Engineering (IRC4SE2) Zhengzhou University Zhengzhou Henan China
Yue Zhang
State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources; College of Chemistry Xinjiang University Urumqi Xinjiang China
Limin Deng
State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources; College of Chemistry Xinjiang University Urumqi Xinjiang China
Lang Liu
State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources; College of Chemistry Xinjiang University Urumqi Xinjiang China
Sen Dong
State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources; College of Chemistry Xinjiang University Urumqi Xinjiang China
Yuliang Cao
State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources; College of Chemistry Xinjiang University Urumqi Xinjiang China
Abstract Semicoke, a coal pyrolysis product, is a cost‐effective and high‐yield precursor for hard carbon used as anode in sodium‐ion batteries (SIBs). However, as a thermoplastic precursor, semicoke inevitably graphitizes during high‐temperature carbonization, so it is not easy to form the hard carbon structure. Herein, we propose an oxidation‐crosslinking strategy to realize fusion‐to‐solid‐state pyrolysis of semicoke. The semicoke is first preoxidized using a modified alkali‐oxygen oxidation method to enrich its surface with carboxyl groups, which are localization points and the cross‐linking reactions occur with citric acid to build the semicoke precursor with homogeneous and abundant ‐C‐(O)–O‐ groups (up to 21 at% oxygen content). The ‐C‐(O)–O‐ groups effectively prevent the rearrangement of carbon microcrystals in semicoke during carbonization, resulting in the formation of an abundant pseudographite structure with larger carbon interlayer spacing and micropores. The optimized semicoke‐based hard carbon shows both a high initial Coulombic efficiency of 81% and a specific capacity of 307 mAh g−1, with low‐voltage plateau capacity increased to 2.5 times, compared to that of the unmodified semicoke carbon. By the combination of detailed discharge curves and in situ X‐ray diffraction analysis, the plateau capacity of semicoke‐based hard carbon is mainly derived from interlayer intercalation of Na+ ion. The proposed oxidation‐crosslinking strategy can contribute to the usage of low‐cost and high‐performance hard carbons in advanced SIBs.
