Capacity and Mechanisms of Phosphate Adsorption on Lanthanum-Modified Dewatered Sludge-Based Biochar

Abstract

Using sewage sludge to produce biochar-based adsorbents to remove phosphate (P) from water can be a sustainable and cost-effective method of waste management. However, the adsorption efficiency of sewage sludge biochar is not high. In this study, lanthanum-modified sludge-based biochar (La-SBBC) was synthesized by combining lanthanum nitrate with dewatered sludge. La-SBBC exhibited the highest removal efficiency of 99.06% for an initial P concentration of 15 mg/L at pH 3.0 with a dosage of 1.3 g/L. The maximum adsorption capacity of La-SBBC for P was 152.77 mg/g at 35 °C. The adsorption process followed the pseudo-second-order kinetic model (R2 ≥ 0.973) and the Freundlich isothermal adsorption model (R2 ≥ 0.928). Multilayer chemisorption was identified as the controlling process. The primary mechanisms of P adsorption by La-SBBC involved electrostatic interactions, precipitation, and inner sphere complexation. Thermodynamic analysis revealed that the adsorption process of La-SBBC was a spontaneous endothermic reaction. The fixed-bed experiment demonstrated that La-SBBC had significant practical utility. La-SBBC maintained 76.6% of the original P removal efficiency after six cycles. Therefore, La-SBBC can be used as a promising adsorbent for P in practical applications.

Keywords

• dewatered sludge
• lanthanum
• La-modified sludge-based biochar
• phosphate
• adsorption