To optimized various parameters of Hopcalite catalysts in the synthetic processes for low temperature CO oxidation

Abstract

Carbon monoxide (CO) is very poisonous gasses present in the atmosphere and lower temperature complete oxidation of CO is very important processes for all life support. The automobile vehicles exhaust is one of the major sources of CO produced into the environment. The application of catalytic converter in automobile vehicles reduces the toxic gasses emission. There are lots of catalysts used in the catalytic converter for CO oxidation purposes among these catalysts the Hopcalite (CuMnOx) is one of the oldest and best-known catalysts for low temperature CO oxidation. The hopcalite catalyst is prepared by the co-precipitation method and preparation parameters like magnetic shaker shaking speed, shaking time, shaking temperature and pH has an influence on the activity of resultant catalysts. The activity of catalyst was measured in reactive calcinations (RC) conditions at the presence of (1.5% CO) and air. The reaction temperature was increased from room temperature to higher temperature at which the total oxidation of CO was achieved. The characterizations of catalysts are done by several techniques like XRD, FTIR, BET and SEM-EDX. These results are interpreted in terms of structure the active catalyst. The reusability of CuMnOx catalyst was also tested and also found that this catalyst does not show any high level of significant change in its catalytic performances even after reuses.

Keywords

• CuMnOx catalyst
• Carbon monoxide
• Co-precipitation method
• Characterization and reactive calcinations