Nature Communications (May 2022)

Coordination environment tuning of nickel sites by oxyanions to optimize methanol electro-oxidation activity

  • Shanlin Li,
  • Ruguang Ma,
  • Jingcong Hu,
  • Zichuang Li,
  • Lijia Liu,
  • Xunlu Wang,
  • Yue Lu,
  • George E. Sterbinsky,
  • Shuhu Liu,
  • Lei Zheng,
  • Jie Liu,
  • Danmin Liu,
  • Jiacheng Wang

DOI
https://doi.org/10.1038/s41467-022-30670-4
Journal volume & issue
Vol. 13, no. 1
pp. 1 – 11

Abstract

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Coordination environments around metal sites are important in electrocatalysis. Here, Ni metalloid oxidation produces oxyanion doped amorphous Ni-oxyhydroxides where substitution with phosphorus is found to boost methanol electrooxidation activity.