Acta Crystallographica Section E (Mar 2012)

N-(9,9-Dipropyl-9H-fluoren-2-yl)-7-(piperidin-1-yl)-2,1,3-benzothiadiazol-4-amine

  • Edward R. T. Tiekink,
  • Seik Weng Ng,
  • M. N. K. Prasad Bolisetty,
  • K. R. Justin Thomas

DOI
https://doi.org/10.1107/S1600536812008239
Journal volume & issue
Vol. 68, no. 3
pp. o911 – o912

Abstract

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In the title compound, C30H34N4S, each of the benzothiadiazole and fluorene fused ring systems is almost planar (r.m.s. deviations = 0.010 and 0.013 Å, respectively) and they are inclined to each other with a dihedral angle of 61.69 (3)°; the S atom is directed away from the rest of the molecule. Each of the benzothiadiazole ring N atoms forms a significant intramolecular contact, i.e. N—H...N or C—H...N. In the crystal, linear supramolecular chains along the c axis are generated by C—H...N interactions involving the tertiary amine N atom.