International Journal of Molecular Sciences (Jan 2015)

Mechanical and Anticorrosive Properties of Graphene/Epoxy Resin Composites Coating Prepared by in-Situ Method

  • Zhiyi Zhang,
  • Wenhui Zhang,
  • Diansen Li,
  • Youyi Sun,
  • Zhuo Wang,
  • Chunling Hou,
  • Lu Chen,
  • Yang Cao,
  • Yaqing Liu

DOI
https://doi.org/10.3390/ijms16012239
Journal volume & issue
Vol. 16, no. 1
pp. 2239 – 2251

Abstract

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The graphene nanosheets-based epoxy resin coating (0, 0.1, 0.4 and 0.7 wt %) was prepared by a situ-synthesis method. The effect of polyvinylpyrrolidone/reduced graphene oxide (PVP-rGO) on mechanical and thermal properties of epoxy resin coating was investigated using nanoindentation technique and thermogravimetric analysis, respectively. A significant enhancement (ca. 213% and 73 °C) in the Young modulus and thermal stability of epoxy resin coating was obtained at a loading of 0.7 wt %, respectively. Furthermore, the erosion resistance of graphene nanosheets-based epoxy resin coating was investigated by electrochemical measurement. The results showed also that the Rrcco (ca. 0.3 mm/year) of graphene nanosheets-based epoxy resin coating was far lower than neat epoxy resin (1.3 mm/year). Thus, this approach provides a novel route for improving erosion resistance and mechanical-thermal stability of polymers coating, which is expected to be used in mechanical-thermal-corrosion coupling environments.

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