Differential Capacity as a Tool for SOC and SOH Estimation of Lithium Ion Batteries Using Charge/Discharge Curves, Cyclic Voltammetry, Impedance Spectroscopy, and Heat Events: A Tutorial

Abstract

State-of-charge (SOC) and state-of-health (SOH) of different cell chemistries were investigated using long-time cycle tests. This practical guide illustrates how differential capacity dQ/dU (capacitance) obtained from discharge curves, impedance spectra, and cyclic voltammograms can be used for the instant diagnosis of lithium-ion batteries without fully charging and discharging the cell. The increase of dU/dQ is an early indicator of upcoming heat events and deep discharge. The criterion dQ/dU = dU/dQ = 1 could serve as an indicator for “full charge”. The frequency response of capacitance correlates with the available charge of the battery and reflects overcharge events and deep discharges long before the battery fails. It is not necessary to measure down to extremely low frequencies because the charge transfer pseudocapacitance of around 10 Hz reflects well the SOC. Computer-aided calculation methods for the evaluation of measurements in industrial environments and for the training of students are presented.

Keywords

• capacitance
• state-of-charge determination
• state-of-health
• aging
• lithium-ion battery