CHIMIA (Jun 2012)

Photoredox Catalysis for Polymerization Reactions

  • Jacques Lalevée,
  • Mohamad-Ali Tehfe,
  • Fabrice Morlet-Savary,
  • Bernadette Graff,
  • Frédéric Dumur,
  • Didier Gigmes,
  • Nicolas Blanchard,
  • Jean-Pierre Fouassier

DOI
https://doi.org/10.2533/chimia.2012.439
Journal volume & issue
Vol. 66, no. 6

Abstract

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Photoredox catalysis is now well-known in organic synthesis for the formation of free radicals under very soft irradiations conditions (e.g. sunlight, household fluorescence or LED bulbs, Xe lamp). This method has been introduced here to the polymer chemistry area to initiate ring opening polymerizations (ROP) or free radical polymerizations (FRP). The present paper will give an up-to date situation of the photocatalyst achievements in FRP and ROP.

Keywords