Acta Crystallographica Section E (Jun 2014)
N′-[(4Z)-1-(3-Methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)hexyl]benzenesulfonohydrazide
Abstract
In the title compound, C22H26N4O3S, the dihedral angle between the pyrazoloneand phenyl rings is 21.73 (4)°. The benzensulfonohydrazide group adopts a gauche conformation about the N—N vector. The C—N—N—S torsion angle is −109.88 (13)°. The molecule exists as the enamine tautomeric form (C=C—NH). An intramolecular N—H...O=C hydrogen bond occurs. In the crystal, molecules are linked by pairs of N—H...O=C hydrogen bonds, forming centrosymmetric dimers.