Nature Communications (Apr 2022)

Experimental evidence of tetrahedral symmetry breaking in SiO2 glass under pressure

  • Yoshio Kono,
  • Koji Ohara,
  • Nozomi M. Kondo,
  • Hiroki Yamada,
  • Satoshi Hiroi,
  • Fumiya Noritake,
  • Kiyofumi Nitta,
  • Oki Sekizawa,
  • Yuji Higo,
  • Yoshinori Tange,
  • Hirokatsu Yumoto,
  • Takahisa Koyama,
  • Hiroshi Yamazaki,
  • Yasunori Senba,
  • Haruhiko Ohashi,
  • Shunji Goto,
  • Ichiro Inoue,
  • Yujiro Hayashi,
  • Kenji Tamasaku,
  • Taito Osaka,
  • Jumpei Yamada,
  • Makina Yabashi

DOI
https://doi.org/10.1038/s41467-022-30028-w
Journal volume & issue
Vol. 13, no. 1
pp. 1 – 8

Abstract

Read online

Understanding the structural origin of the anomalous properties of SiO2 liquid and glass at high pressures is fundamental in wide range of scientific fields. Here, the authors find experimental evidence of a bimodal behavior in the translational order of silicon’s second shell and breaking of local tetrahedral symmetry in SiO2 glass under pressure.