Synthesis and structure of novel tripodal ligands based on tetrazol-5-thioles

Abstract

Novel tripodal ligands (R1N4CS)3CH, where R1 = Me, Ph, were synthesised by alkylation of 1-R-tetrazol-5-thioles with iodoform in alkaline media. These ligands were identified based on data of elemental analysis, nuclear magnetic resonance spectroscopy, thermal analysis, and X-ray diffraction analysis of single crystals.

Keywords

• multipodal ligands
• tetrazol-5-thioles
• alkylation
• x-ray diffraction analysis