Desilication tuning of In/Hβ catalysts for sulfur- and steam-resistant CH4-SCR of NO

Jiuhu Zhao; Huiying Li; Yungang Wang; Rongshu Zhu; Senlin Sun; Jingwen Zhang; Chaolin Li; Mei Hong

Catalysis Communications (Feb 2023)

Desilication tuning of In/Hβ catalysts for sulfur- and steam-resistant CH4-SCR of NO

Jiuhu Zhao,
Huiying Li,
Yungang Wang,
Rongshu Zhu,
Senlin Sun,
Jingwen Zhang,
Chaolin Li,
Mei Hong

Affiliations

Jiuhu Zhao: State Key Laboratory of Urban Water Resource and Environment, Shenzhen Key Laboratory of Organic Pollution Prevention and Control, School of Civil and Environmental Engineering, Harbin Institute of Technology Shenzhen, Shenzhen 518055, PR China; State Key Laboratory of Chemical Oncogenomics, Guangdong Provincial Key Laboratory of Nano-Micro Materials Research, School of Chemical Biology & Biotechnology, Peking University Shenzhen Graduate School (PKUSZ), Shenzhen 518055, PR China
Huiying Li: State Key Laboratory of Urban Water Resource and Environment, Shenzhen Key Laboratory of Organic Pollution Prevention and Control, School of Civil and Environmental Engineering, Harbin Institute of Technology Shenzhen, Shenzhen 518055, PR China
Yungang Wang: Everbright Environmental Technology Research Institute (Shenzhen) Co., Ltd, Shenzhen 518071, PR China
Rongshu Zhu: State Key Laboratory of Urban Water Resource and Environment, Shenzhen Key Laboratory of Organic Pollution Prevention and Control, School of Civil and Environmental Engineering, Harbin Institute of Technology Shenzhen, Shenzhen 518055, PR China; Corresponding authors.
Senlin Sun: State Key Laboratory of Urban Water Resource and Environment, Shenzhen Key Laboratory of Organic Pollution Prevention and Control, School of Civil and Environmental Engineering, Harbin Institute of Technology Shenzhen, Shenzhen 518055, PR China
Jingwen Zhang: State Key Laboratory of Urban Water Resource and Environment, Shenzhen Key Laboratory of Organic Pollution Prevention and Control, School of Civil and Environmental Engineering, Harbin Institute of Technology Shenzhen, Shenzhen 518055, PR China
Chaolin Li: State Key Laboratory of Urban Water Resource and Environment, Shenzhen Key Laboratory of Organic Pollution Prevention and Control, School of Civil and Environmental Engineering, Harbin Institute of Technology Shenzhen, Shenzhen 518055, PR China; Corresponding authors.
Mei Hong: State Key Laboratory of Chemical Oncogenomics, Guangdong Provincial Key Laboratory of Nano-Micro Materials Research, School of Chemical Biology & Biotechnology, Peking University Shenzhen Graduate School (PKUSZ), Shenzhen 518055, PR China; Corresponding authors.

Journal volume & issue: Vol. 175
p. 106619

Abstract

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Mesoporous In/Hβ-X series catalysts were prepared by desilication method with tetrapropylammonium hydroxide (TPAOH) and indium incorporation for selective catalytic reduction of NO with methane (CH4-SCR). The post desilication treatment conditions for preparing In/Hβ-X were optimized. Etching time is the most important desilication parameter influencing the resulting CH4-SCR performance of the catalyst. The In/Hβ-3 sample which was etched for 3 h presents the highest NOx conversion, 22% higher than In/H-Beta counterparts using commercial microporous beta. Obvious analysis reveals that besides generating mesopores, controlled desilication can modulate the proportion of InO+ active sites and surface oxygen species, allowing more active sites to be exposed.

Published in Catalysis Communications

ISSN: 1566-7367 (Print); 1873-3905 (Online)
Publisher: Elsevier
Country of publisher: Netherlands
LCC subjects: Science: Chemistry
Website: https://www.journals.elsevier.com/catalysis-communications

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