High-density polyethylene/EPDM rubber blend composites of boron compounds for neutron shielding application

Abstract

Novel materials with neutron shielding property were fabricated by incorporating boron compounds into highdensity polyethylene (HDPE)/Ethylene propylene diene monomer rubber (EPDM) blends. A detailed investigation on the morphological, thermal, mechanical, and neutron attenuation properties of suitable proportion of HDPE/EPDM blend with boric acid (BA), boron carbide (BC), and nano boron carbide (NBC) were performed. Morphology of the 20 wt% of EPDM shows better distribution in HDPE matrix. BA filler is localised in the HDPE phase, while NBC shows uniform distribution in HDPE/EPDM blend compared to its micro counterpart. There is a reduction in the tensile strength and modulus with the incorporation of EPDM in HDPE, whereas the ductility of HDPE is enhanced. A significant increase in the tensile toughness of the HDPE/EPDM blend with lower tensile strength and modulus is observed for BA, and BC filled composites. Moreover, HDPE/EPDM composites with NBC show only a marginal increase in the tensile toughness, tensile strength, and modulus. Comparison of the Young’s modulus of the HDPE/EPDM blends with theoretical models indicates trends similar to the Coran model. The BA and BC filled composites follow the lower bound series model, whereas NBC composites show behaviour similar to the Halpin Tsai model. Total thermal neutron macroscopic cross-section (0.025 MeV energy neutrons) of 10 cm–1 and mean free path of 0.1 cm was obtained for 20 wt% NBC HDPE/EPDM composites.

Keywords

• polymer composites
• thermoplastic elastoemers
• borated polymers
• nanocomposites
• mechanical properties