The color systematics of volcanic ashfall samples in estimating eruption sequences: a case study of the 2017–2018 eruption at Shinmoe-dake, Kirishima volcano, Southwest Japan

Abstract

Abstract The color of pyroclasts is fundamental, because it reflects various magma properties and eruption processes, including particle morphology, chemistry, and petrological characteristics. However, deriving the componentry ratio (CR) of pyroclasts for ongoing eruption monitoring remains challenging due to the lack of a robust quantitative standard. The derivation of the CR, as well as other petrological analyses, is too laborious and time-consuming to introduce as a sustainable monitoring method. To address this, we employed spectroscopic colorimetry to rapidly and quantitatively describe eruptive product colors, enabling CR derivation based on clear, objective standards for ash particle classification. Through color spectroscopy of bulk and sieved ash samples, we analyzed the major size fraction for time-series samples during the waxing stage of the 2017–2018 Shinmoe-dake eruption in Kirishima volcano, Southwest Japan. Our findings reveal that the color changes in bulk ash systematically changed with the evolution of componentry. This temporal color change was due to an increase in the amount of vesicular particles with clear glass against dark angular lava particles, as well as a grain size change, which we interpret as an indication of a transition from phreatic/phreatomagmatic to magmatic eruption. Subsequently, the color of the ash changed when the amount of different lava particles increased gradually, coinciding with a shift toward a more dominant effusion of lava. As the lava effusion continued, a slight reddening of the ash, indiscernible to the naked eye, was clearly detected by the spectrometer before the onset of intermittent Vulcanian eruptions. We interpreted this reddening as oxidation resulting from decreased ascent speed and caprock formation, which accumulates overpressure for Vulcanian explosions. These results highlight the potential of rapid, objective color value and componentry derivation for sustainable quasi-real-time monitoring of ongoing eruption materials. Graphical Abstract

Keywords

• Volcanic ash
• Colorimetry
• Microspectroscopy
• Componentry
• Eruption sequence