Acta Crystallographica Section E (May 2012)

Diethyl 4-[5-(4-chlorophenyl)-1H-pyrazol-4-yl]-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate

  • Wan-Sin Loh,
  • Shridhar Malladi,
  • A. M. Vijesh,
  • Hoong-Kun Fun,
  • Arun M. Isloor

DOI
https://doi.org/10.1107/S160053681201344X
Journal volume & issue
Vol. 68, no. 5
pp. o1289 – o1290

Abstract

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In the title compound, C22H24ClN3O4, intramolecular C—H...O and C—H...N hydrogen bonds form S(9) and S(7) ring motifs, respectively. The 1,4-dihydropyridine ring adopts a flattened boat conformation. The benzene ring makes a dihedral angle of 33.36 (6)° with the pyrazole ring. In the crystal, pairs of N—H...N hydrogen bonds link the molecules into inversion dimers. The dimers are stacked in column along the a axis through N—H...O and C—H...N hydrogen bonds. The crystal packing also features C—H...π interactions involving the pyrazole ring.