Alkali−Silica Activity and Inhibition Measures of Concrete Aggregate in Northwest China

Abstract

The alkali−silica reaction (ASR)-induced expansion of mortar bars containing four types of aggregates originating from different regions in northwest China was studied. The chemical composition, mineral composition, vitreous and amorphous substances, and expansion rates were determined using X-ray fluorescence, X-ray diffraction, polarizing microscope images, and the accelerated mortar bar test (AMBT). The inhibitory effects of fly ash and silica fume on the aggregate activity were evaluated. The binary mortar mixes were produced and tested, containing cement and fly ash or silica fume as the partial cement replacement. The microstructure and composition of the ASR products were analyzed by scanning electron microscope energy dispersive spectroscopy (SEM–EDS). The results show that all four types of aggregates exhibited an alkali activity, and that all expansion rates on the 14th day were higher than the standard of 0.1%. The lowest and highest values were 0.2% and 0.3%, respectively. The primary constituent in the chemical compositions of these aggregates was found to be silica. Polarization microscopy also confirmed that they contained alkali-active cryptolites. Fly ash and silica fume could both inhibit alkali activity expansion and the silica fume exhibited a superior inhibition effect. When the fly ash and silica fume contents were 20% and 10%, respectively, the expansion rates of the mortar bar on the 14th day were all less than 0.03%.

Keywords

• alkali aggregate reactions
• fly ash
• silica fume