Química Nova (Jan 2013)

Least squares regression with errors in both variables: case studies

  • Elcio Cruz de Oliveira,
  • Paula Fernandes de Aguiar

DOI
https://doi.org/10.1590/S0100-40422013000600025
Journal volume & issue
Vol. 36, no. 6
pp. 885 – 889

Abstract

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Analytical curves are normally obtained from discrete data by least squares regression. The least squares regression of data involving significant error in both x and y values should not be implemented by ordinary least squares (OLS). In this work, the use of orthogonal distance regression (ODR) is discussed as an alternative approach in order to take into account the error in the x variable. Four examples are presented to illustrate deviation between the results from both regression methods. The examples studied show that, in some situations, ODR coefficients must substitute for those of OLS, and, in other situations, the difference is not significant.

Keywords