Materials Research Express (Jan 2020)

Effect of Sn content on the mechanical properties and corrosion behavior of Mg-3Al-xSn alloys

  • Zhaochen Yu,
  • Qianfei Huang,
  • Wentao Zhang,
  • Chao Luo,
  • Hongyu Guan,
  • Yang Chen,
  • Honggun Song,
  • Zhi Hu,
  • Chassagne Luc

DOI
https://doi.org/10.1088/2053-1591/aba149
Journal volume & issue
Vol. 7, no. 7
p. 076505

Abstract

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The effect of Sn content on the mechanical properties and corrosion behavior of Mg-3Al-xSn alloys was investigated by SEM-EDXS, XRD, electrochemical measurements, and scanning Kelvin probe force microscopy (SKPFM). The results showed that when the Sn content was 1.4 wt%, Sn dissolved in the α -Mg matrix and then precipitated as an intermetallic compound (Mg _2 Sn). The combined results of mass loss, hydrogen evolution, and electrochemical measurements indicated that Mg-3Al-1Sn had a low corrosion rate. The SKPFM results showed that the Volta potential of Mg _2 Sn particles, Al-Mn, and β -Mg _17 Al _12 phases were 100, 80, and 50 mV higher than the matrix, respectively. Therefore, the Mg _2 Sn phase that formed in Mg-3Al-xSn served as a local cathode due to its high potential, which accelerated microgalvanic corrosion along with the secondary local cathode (Al-Mn). The Sn solution strengthening and secondary phase strengthening (fine Mg _2 Sn particles) improved the mechanical properties of the Mg-3Al-xSn alloys.

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