Acta Crystallographica Section E (Jul 2008)

Hexaaquamagnesium(II) bis(d-camphor-10-sulfonate)

  • Dejan Jeremić,
  • Goran N. Kaluderović,
  • Ilija Brčeski,
  • Santiago Gómez-Ruiz,
  • Katarina K. Andelković

DOI
https://doi.org/10.1107/S1600536808018047
Journal volume & issue
Vol. 64, no. 7
pp. m952 – m952

Abstract

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The structure of the title complex, [Mg(H2O)6](C10H15O4S)2, consists of regular octahedral [Mg(H2O)6]2+ cations and d-camphor-10-sulfonate anions. A three-dimensional supramolecular architecture is formed via hydrogen-bond interactions [O—H...O = 2.723 (2)–2.833 (2) Å] to give alternating layers of [Mg(H2O)6]2+ cations and d-camphor-10-sulfonate anions. The title compound is isomorphous with the zinc, copper, cadmium and nickel analogues.