Development of a New Arylamination Reaction Catalyzed by Polymer Bound 1,3-(Bisbenzimidazolyl) Benzene Co(II) Complex and Generation of Bioactive Adamanate Amines

Baburajeev Chumadathil Pookunoth; Shilpa Eshwar Rao; Suresha Nayakanahundi Deveshegowda; Prashant Kashinath Metri; Kashifa Fazl-Ur-Rahman; Ganga Periyasamy; Gayathri Virupaiah; Babu Shubha Priya; Vijay Pandey; Peter E. Lobie; Rangappa Knchugarakoppal Subbegowda; Basappa

doi:10.3390/catal10111315

Catalysts (Nov 2020)

Development of a New Arylamination Reaction Catalyzed by Polymer Bound 1,3-(Bisbenzimidazolyl) Benzene Co(II) Complex and Generation of Bioactive Adamanate Amines

Baburajeev Chumadathil Pookunoth,
Shilpa Eshwar Rao,
Suresha Nayakanahundi Deveshegowda,
Prashant Kashinath Metri,
Kashifa Fazl-Ur-Rahman,
Ganga Periyasamy,
Gayathri Virupaiah,
Babu Shubha Priya,
Vijay Pandey,
Peter E. Lobie,
Rangappa Knchugarakoppal Subbegowda,
Basappa

Affiliations

Baburajeev Chumadathil Pookunoth: Department of Chemistry, Central College Campus, Bangalore University, Bangalore 560001, Karnataka, India
Shilpa Eshwar Rao: Department of Chemistry, Central College Campus, Bangalore University, Bangalore 560001, Karnataka, India
Suresha Nayakanahundi Deveshegowda: Laboratory of Chemical Biology, Department of Studies in Organic Chemistry, University of Mysore, Manasagangotri, Mysore 570006, Karnataka, India
Prashant Kashinath Metri: Laboratory of Chemical Biology, Department of Studies in Organic Chemistry, University of Mysore, Manasagangotri, Mysore 570006, Karnataka, India
Kashifa Fazl-Ur-Rahman: Department of Chemistry, Central College Campus, Bangalore University, Bangalore 560001, Karnataka, India
Ganga Periyasamy: Department of Chemistry, Central College Campus, Bangalore University, Bangalore 560001, Karnataka, India
Gayathri Virupaiah: Department of Chemistry, Central College Campus, Bangalore University, Bangalore 560001, Karnataka, India
Babu Shubha Priya: Laboratory of Chemical Biology, Department of Studies in Organic Chemistry, University of Mysore, Manasagangotri, Mysore 570006, Karnataka, India
Vijay Pandey: Tsinghua Berkeley Shenzhen Institute, Tsinghua Shenzhen International Graduate School, Shenzhen 518055, China
Peter E. Lobie: Tsinghua Berkeley Shenzhen Institute, Tsinghua Shenzhen International Graduate School, Shenzhen 518055, China
Rangappa Knchugarakoppal Subbegowda: Institution of Excellence, Vijnana Bhavan, University of Mysore, Mysore 570005, Karnataka, India
Basappa: Department of Chemistry, Central College Campus, Bangalore University, Bangalore 560001, Karnataka, India

DOI: https://doi.org/10.3390/catal10111315
Journal volume & issue: Vol. 10, no. 11
p. 1315

Abstract

Read online

We herein report the preparation and characterization of an inexpensive polymer supported 1,3-bis(benzimidazolyl)benzeneCo(II) complex [PS-Co(BBZN)Cl2] as a catalyst by using the polymer (divinylbenzene cross-linked chloromethylated polystyrene), on which 1,3-bis(benzimidazolyl)benzeneCo(II) complex (PS-Co(BBZN)Cl2) has been immobilized. This catalyst was employed to develop arylamination reaction and robustness of the same reaction was demonstrated by synthesizing various bioactive adamantanyl-tethered-biphenylamines. Our synthetic methodology was much improved than reported methods due to the use of an inexpensive and recyclable catalyst.

Published in Catalysts

ISSN: 2073-4344 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Technology: Chemical technology; Science: Chemistry
Website: https://www.mdpi.com/journal/catalysts

About the journal

Abstract

Keywords