Acta Crystallographica Section E (Dec 2009)

trans-Dichloridobis[tris(4-methoxyphenyl)phosphine]palladium(II) benzene monosolvate

  • Cedric W. Holzapfel,
  • Charmaine van Blerk

DOI
https://doi.org/10.1107/S1600536809046261
Journal volume & issue
Vol. 65, no. 12
pp. m1536 – m1536

Abstract

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The structure of the title compound, [PdCl2(C21H21O3P)2]·C6H6, shows a square-planar geometry for the PdII atom within a Cl2[P(PhOMe)3]2 ligand set. The crystal structure contains benzene as solvent. The PdII atom sits on a centre of inversion and therefore the asymmetric unit contains the PdII atom, one Cl atom, one tris(4-methoxyphenyl)phosphine ligand and one half of the benzene solvent molecule.