Towards rare-earth-free white light-emitting diode devices based on the combination of dicyanomethylene and pyranine as organic dyes supported on zinc single-layered hydroxide

Abstract

A new luminescent composite film resulting from the dispersion of luminescent organic dyes in a single-layered hydroxide (SLH)-type inorganic matrix has been developed. Two fluorescent organic dyes emitting visible light upon blue LED excitation were investigated in this study: dicyanomethylene (DCM) and pyranine (HPTS). These dyes exhibit broad emission bands that cover a large part of the visible spectrum. The concept developed in our work consisted in keeping SLH in its wet form to ensure a good dispersion of the fluorescent dyes prior to immobilizing the hybrid materials in a silicone polymer to achieve luminescent composite films. We demonstrate that these coatings stacked upon each other and placed above a blue LED lead to white-light emission with suitable photometric parameters for applications in lighting or display devices: colour temperature of 5409 K and colour rendering index (CRI) of 81.

Keywords

• dicyanomethylene (DCM)
• hybrid luminescent films
• light-emitting diode (LED)
• pyranine
• zinc hydroxyacetate