Journal of Saudi Chemical Society (Jul 2017)

Efficient synthesis of dibenzyl carbonates from benzyl halides and Cs2CO3

  • Yuxuan He,
  • Jing Sun,
  • Fang-Jie Guo,
  • Xiangchen Fang,
  • Ming-Dong Zhou

DOI
https://doi.org/10.1016/j.jscs.2017.01.003
Journal volume & issue
Vol. 21, no. 5
pp. 583 – 586

Abstract

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A simple and efficient protocol for the synthesis of dibenzyl carbonates has been developed. The reaction was accomplished using benzyl halides and Cs2CO3 as the starting materials in the presence of atmospheric pressure of CO2, affording a variety of the dibenzyl carbonates in good to excellent yields under rather mild conditions.

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