Mn(iii)-Catalyzed Radical Reactions of 1,3-Dicarbonyl Compounds and Cyclopropanols with Vinyl Azides for Divergent Synthesis of Azaheterocycles
Shunsuke Chiba
Affiliations
Shunsuke Chiba
Nanyang Technological University, School of Physical and Mathematical Sciences, Division of Chemistry and Biological Chemistry, 21 Nanyang Link, Singapore 637371, Singapore
Mn(iii)-catalyzed formal [3+2]- and [3+3]-annulations have been developed using readily available vinyl azides with 1,3-dicarbonyl compounds and cyclopropanols. Vinyl azides were successfully applied as a three-atom unit including one nitrogen to prepare various azaheterocycles via Mn(iii)-catalyzed radical reactions.
