Synthesis, Spectroscopic, Thermal and Catalytic Properties of Four New Metal (II) Complexes with Selected N- and O-Donor Ligands

Agnieszka Czylkowska; Bartłomiej Rogalewicz; Anita Raducka; Natalia Błaszczyk; Tomasz Maniecki; Kinga Wieczorek; Paweł Mierczyński

doi:10.3390/ma13143217

Materials (Jul 2020)

Synthesis, Spectroscopic, Thermal and Catalytic Properties of Four New Metal (II) Complexes with Selected N- and O-Donor Ligands

Agnieszka Czylkowska,
Bartłomiej Rogalewicz,
Anita Raducka,
Natalia Błaszczyk,
Tomasz Maniecki,
Kinga Wieczorek,
Paweł Mierczyński

Affiliations

Agnieszka Czylkowska: Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland
Bartłomiej Rogalewicz: Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland
Anita Raducka: Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland
Natalia Błaszczyk: Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland
Tomasz Maniecki: Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland
Kinga Wieczorek: Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland
Paweł Mierczyński: Institute of General and Ecological Chemistry, Faculty of Chemistry, Lodz University of Technology, Zeromskiego 116, 90-924 Lodz, Poland

DOI: https://doi.org/10.3390/ma13143217
Journal volume & issue: Vol. 13, no. 14
p. 3217

Abstract

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Four solid compounds with formulae: Co(OAc)2(Im)·H2O (I), Ni(OAc)2(Im)1.5·2H2O (II), Cu2(OAc)4(Im) (III) and Zn(OAc)2(Im)·H2O (IV) (where: Im = 1H-Imidazole) were prepared and characterized by chemical and elemental analysis, powder X-ray diffraction patterns and FTIR spectroscopy. Catalytic properties of each complex for styrene oxidation reaction were investigated. Furthermore, thermal properties of compounds were studied using the TG-DTG and DSC techniques under dry air atmosphere. Additionally, volatile thermal decomposition and fragmentation products were also investigated using the TG-FTIR spectra in air.

Published in Materials

ISSN: 1996-1944 (Online)
Publisher: MDPI AG
Country of publisher: Switzerland
LCC subjects: Technology: Electrical engineering. Electronics. Nuclear engineering; Technology: Engineering (General). Civil engineering (General); Science: Natural history (General): Microscopy; Science: Physics: Descriptive and experimental mechanics
Website: http://www.mdpi.com/journal/materials/

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