Nature Communications (Jan 2020)
Vibrational wavepacket dynamics in Fe carbene photosensitizer determined with femtosecond X-ray emission and scattering
- Kristjan Kunnus,
- Morgane Vacher,
- Tobias C. B. Harlang,
- Kasper S. Kjær,
- Kristoffer Haldrup,
- Elisa Biasin,
- Tim B. van Driel,
- Mátyás Pápai,
- Pavel Chabera,
- Yizhu Liu,
- Hideyuki Tatsuno,
- Cornelia Timm,
- Erik Källman,
- Mickaël Delcey,
- Robert W. Hartsock,
- Marco E. Reinhard,
- Sergey Koroidov,
- Mads G. Laursen,
- Frederik B. Hansen,
- Peter Vester,
- Morten Christensen,
- Lise Sandberg,
- Zoltán Németh,
- Dorottya Sárosiné Szemes,
- Éva Bajnóczi,
- Roberto Alonso-Mori,
- James M. Glownia,
- Silke Nelson,
- Marcin Sikorski,
- Dimosthenis Sokaras,
- Henrik T. Lemke,
- Sophie E. Canton,
- Klaus B. Møller,
- Martin M. Nielsen,
- György Vankó,
- Kenneth Wärnmark,
- Villy Sundström,
- Petter Persson,
- Marcus Lundberg,
- Jens Uhlig,
- Kelly J. Gaffney
Affiliations
- Kristjan Kunnus
- PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
- Morgane Vacher
- Department of Chemistry - Ångström laboratory, Uppsala University
- Tobias C. B. Harlang
- Department of Chemical Physics, Lund University
- Kasper S. Kjær
- PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
- Kristoffer Haldrup
- Department of Physics, Technical University of Denmark
- Elisa Biasin
- PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
- Tim B. van Driel
- LCLS, SLAC National Accelerator Laboratory
- Mátyás Pápai
- Department of Chemistry, Technical University of Denmark
- Pavel Chabera
- Department of Chemical Physics, Lund University
- Yizhu Liu
- Department of Chemical Physics, Lund University
- Hideyuki Tatsuno
- Department of Chemical Physics, Lund University
- Cornelia Timm
- Department of Chemical Physics, Lund University
- Erik Källman
- Department of Chemistry - Ångström laboratory, Uppsala University
- Mickaël Delcey
- Department of Chemistry - Ångström laboratory, Uppsala University
- Robert W. Hartsock
- PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
- Marco E. Reinhard
- PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
- Sergey Koroidov
- PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
- Mads G. Laursen
- Department of Physics, Technical University of Denmark
- Frederik B. Hansen
- Department of Physics, Technical University of Denmark
- Peter Vester
- Department of Physics, Technical University of Denmark
- Morten Christensen
- Department of Physics, Technical University of Denmark
- Lise Sandberg
- Department of Physics, Technical University of Denmark
- Zoltán Németh
- Wigner Research Centre for Physics, Hungarian Academy of Sciences
- Dorottya Sárosiné Szemes
- Wigner Research Centre for Physics, Hungarian Academy of Sciences
- Éva Bajnóczi
- Wigner Research Centre for Physics, Hungarian Academy of Sciences
- Roberto Alonso-Mori
- LCLS, SLAC National Accelerator Laboratory
- James M. Glownia
- LCLS, SLAC National Accelerator Laboratory
- Silke Nelson
- LCLS, SLAC National Accelerator Laboratory
- Marcin Sikorski
- LCLS, SLAC National Accelerator Laboratory
- Dimosthenis Sokaras
- SSRL, SLAC National Accelerator Laboratory
- Henrik T. Lemke
- LCLS, SLAC National Accelerator Laboratory
- Sophie E. Canton
- ELI-ALPS, ELI-HU Non-Profit Ltd.
- Klaus B. Møller
- Department of Chemistry, Technical University of Denmark
- Martin M. Nielsen
- Department of Physics, Technical University of Denmark
- György Vankó
- Wigner Research Centre for Physics, Hungarian Academy of Sciences
- Kenneth Wärnmark
- Centre for Analysis and Synthesis, Department of Chemistry, Lund University
- Villy Sundström
- Department of Chemical Physics, Lund University
- Petter Persson
- Theoretical Chemistry Division, Lund University
- Marcus Lundberg
- Department of Chemistry - Ångström laboratory, Uppsala University
- Jens Uhlig
- Department of Chemical Physics, Lund University
- Kelly J. Gaffney
- PULSE Institute, SLAC National Accelerator Laboratory, Stanford University
- DOI
- https://doi.org/10.1038/s41467-020-14468-w
- Journal volume & issue
-
Vol. 11,
no. 1
pp. 1 – 11
Abstract
Photoinduced non-adiabatic intramolecular processes have important applications but their mechanisms are challenging to explore. Here the authors detect and assign vibrational wavepacket dynamics in a Fe carbene complex by ultrafast X-ray emission spectroscopy and X-ray scattering, resolving nuclear and electronic motion.
