Combination of TiO2-Film Photocatalysis and Ultrafiltration to Treat Wastewater

Abstract

In this study, a combination of TiO2-film photocatalysis reactor and ultrafiltration was used treat the secondary effluent from the manufacturing of thin film transistor-liquid crystal display (TFT-LCD). TiO2 particles, as a photocatalyst, were immobilized on silica glass to form TiO2-film by the sol-gel and dip coating methods. TiO2-film photocatalysis was done within three parameters, including number of coating times of TiO2-film, wavelengths of UV light source, and operating time. During ultrafiltration, the operating pressure and feed water temperature were controlled at 300 KN/m2 and 25°C, respectively. It was found that TiO2-film photocatalysis followed by ultrafiltration increased the removal of total organic carbon (TOC) to 47.13% and 49.94% for 5 KDa and 10 KDa membranes, respectively. It was also found that the process increased the permeate flux rate (ca 23%) for 10 KDa membrane after 6 hours of operation, since some larger organic matter had been broken into small organic matter and some small organic matter had been mineralized into CO2 following TiO2-film photocatalysis. Therefore, combining TiO2-film photocatalysis reactor and ultrafiltration can improve organic wastewater quality and increase the permeate flux of ultrafiltration membrane, which may enhance the recycling and reuse of wastewater.