IUCrData (Oct 2020)

(4′-Chloro-2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)bis(nitrato-κO)zinc(II)

  • Rafael A. Adrian,
  • Daniela Canales,
  • Hadi D. Arman

DOI
https://doi.org/10.1107/S2414314620013449
Journal volume & issue
Vol. 5, no. 10
p. x201344

Abstract

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In the title complex, [Zn(C15H10ClN3)(NO3)2], the central zinc(II) atom is pentacoordinated by two O-bonded nitrate ions and three N atoms of the 4′-chloro-2,2′:6′,2′′-terpyridine ligand in a slightly distorted trigonal–bipyramidal shape. The main feature of the title complex packing is the presence of offset π–π interactions between the terpyridine rings in different layers. This structure constitutes the first known example of a zinc(II) 4-chloroterpyridine complex with coordinating nitrate ions.

Keywords