Synthesis and Characterization of some complex salts of Ti(III) and VO(V) chlorides with pyrrolium , imidazolium , indolium and their benzyl derivative

Abstract

New complexes salts of A2[VOCl5] and A3[TiCl6],where A = , X = H or CH2Ph, were prepared by treatment of above organic salts with metal chloride in (3:1) or (2:1) molar ratio. The new complex salts were characterized by microelemental analysis, conductivity measurements, spectroscopic data (IR and U.V/Visible) as well as the magnetic measurements. These studies confirm that the complex salts are 2:1 electrolytes and the VO (V) or Ti(III) in the anionic moiety of the complex salts achieve octahedral environment.

Keywords

• metal chloride
• microelemental analysis
• anionic moiety