One-Step Fabrication of PtSn/γ-Al₂O₃ Catalysts with La Post-Modification for Propane Dehydrogenation

Abstract

The catalytic dehydrogenation of propane to propene is an alternative technique to supplement the traditional steam cracking and catalytic cracking process for satisfying the continuously increasing demand for propylene downstream products. In this study, the parent PtSn/γ-Al2O3 catalyst was fabricated via the one-step method for the subsequent La post-modification to prepare the catalysts for propane dehydrogenation. The prepared and spent catalysts were characterized by X-ray diffraction (XRD), N2 adsorption–desorption, scanning electron microscope (SEM), NH3 temperature-programmed desorption (NH3-TPD), H2 temperature-programmed desorption (H2-TPR), and thermogravimetric (TG) analysis. The catalytic performance and characterization results demonstrated that the addition of La into the parent catalyst could significantly improve the catalytic performance of the prepared catalyst. Especially, the PtSn-La2.2 catalyst with the 2.2 wt.% La addition exhibited the stable and highest propylene selectivity (>84%) under the investigation time of 800 min. The introduced La exhibits the ability to adjust the textural properties of the obtained catalysts, curb the acidity of support, promote the reduction of Pt species, and reduce the carbon accumulation on the prepared catalysts.

Keywords

• propane dehydrogenation
• lanthanum
• PtSn catalysts
• propylene