Adsorption of cobalt (II) ions from aqueous solution using cow bone and its derivatives: Kinetics, equilibrium and thermodynamic comparative studies

Abstract

Mono-component adsorption of Co2+ ions from simulated industrial water was investigated by using cow bone (CB), cow bone char (CBC), and activated cow bone carbon (ACBC) adsorbents synthesized from raw cow bone as the precursor. The resulting prepared adsorbent materials were then characterized using analytical methods such as: zeta potential measurements, BET surface area, FTIR, SEM, EDS, and XRD analysis. For all synthesized adsorbents, the main compositions were mesopores with the presence of CC, PO32−, CO32 and O-H bonds signifying hydroxyapatite nature of the adsorbents. The isoelectric point (pHIEP) of ACBC was obtained to be 3.59 (lowest among the prepared adsorbents) thereby signifying that ACBC's electrostatic force of attraction was relatively higher between the Co2+ and its surface. The study showed that the pseudo second-order kinetic model had the best correlation for all the adsorption kinetic experimental data for each prepared adsorbent, inferring that the rate-controlling step during the Co2+ ions adsorption onto the prepared adsorbents is chemisorption. The Sips isotherm model excellently predicted the adsorption data for the adsorption of Co2+ ions on the CB adsorbents while the Langmuir isotherm best fitted the equilibrium data of the CBC, and ACBC prepared adsorbents with excellent correlation coefficients, while maximum adsorption capacities, qmax, were obtained to be 52.50, 58.80, and 64.50 mg g−1 for CB, CBC, and ACBC respectively. The study of the thermodynamic properties of the adsorption of Co2+ showed the process was endothermic, non-spontaneous and endogenic for the ACBC adsorbent, while being exothermic for the CB, and CBC adsorbents in addition to having physisorption properties.

Keywords

• Adsorption
• Cow bone
• Cobalt
• Industrial wastewater
• Thermodynamics