Nature Communications (Jun 2022)

Visible light-controlled living cationic polymerization of methoxystyrene

  • Lei Wang,
  • Yupo Xu,
  • Quan Zuo,
  • Haojie Dai,
  • Lei Huang,
  • Meng Zhang,
  • Yongli Zheng,
  • Chunyang Yu,
  • Shaodong Zhang,
  • Yongfeng Zhou

DOI
https://doi.org/10.1038/s41467-022-31359-4
Journal volume & issue
Vol. 13, no. 1
pp. 1 – 11

Abstract

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Photo-controlled living polymerization has received great attention in recent years but the reports on photo-controlled living cationic polymerization are limited. Here, the authors demonstrate a metal-free and visible light-controlled living cationic polymerization using a photocatalyst and a phosphate as the chain transfer agent for the polymerization of 4-methoxystyrene.