Single-Cell Tests to Explore the Reliability of Sofc Installations Operating Offshore

Abstract

This paper studies the robustness of off-shore solid oxide fuel cell (SOFC) installations and the nature and causes of possible cell degradation in marine environments. Two important, cathode-related, impediments to ensuring SOFC reliability in off-shore installations are: cathode degradation due to salt contamination and oxygen depletion in the air supply. Short-term and long-term tests show the effect of salt contamination in the cathode feed on cell performance, and reveal the underlying cause of the degradation seen. SEM/X-ray Diffraction/(XRD) analyses made it possible to identify salt taken up in the cathode microstructure after the short-term testing while the macroscopic cell structure remained intact after the short-term tests. The long-term degradation was found to be more severe, and SEM images showed delamination at the cathode/electrolyte interface with salt present, something that was not seen after long-term testing without salt. The effect of oxygen depletion on the performance was also determined at three different temperatures using I-V curves.

Keywords

• SOFC
• reliability
• contamination
• salt
• oxygen starvation
• concentration polarization